Enamines

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Nature , — List, B. The ying and yang of asymmetric aminocatalysis. Nielsen, M.

Alphabetical Index

Mechanisms in aminocatalysis. Proline-catalyzed direct asymmetric aldol reactions.

Publication details

Northrup, A. The first direct and enantioselective cross-aldol reaction of aldehydes. Bogevig, A. Direct catalytic asymmetric aldol reactions of aldehydes.

Producing and Using Imines and Enamines

Momiyama, N. Bronsted acid catalysis of achiral enamine for regio- and enantioselective nitroso aldol synthesis. Narasaka, K. Generation of cation radicals from enamines and their reactions with olefins. Beeson, T. Enantioselective organocatalysis using SOMO activation.


  1. Imines and Enamines.
  2. Enamines: Synthesis: Structure, and Reactions, Second Edition, - CRC Press Book.
  3. The Challenge of Change: Dealing with the Legacy of the Modern Movement - Proceedings of the 10th International DOCOMOMO Conference.

Science , — Jang, H. Enantioselective organocatalytic singly occupied molecular orbital activation: The enantioselective alpha-enolation of aldehydes.


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  • Koike, T. Kano, T. Metal-free direct asymmetric aminoxylation of aldehydes catalyzed by a binaphthyl-based chiral amine. Pirnot, M. Photoredox activation for the direct beta-arylation of ketones and aldehydes. Zhang, S. Organocatalytic enantioselective beta-functionalization of aldehydes by oxidation of enamines and their application in cascade reactions. Babler, J. The role of imine-enamine tautomerism in effecting cross-aldol condensations. Tetrahedron Lett. Jabin, I.

    Tautomerism of alpha,beta-ethylenic imines and their reactivity toward electrophilic olefins. Wei, Y. Palladium-catalyzed aerobic oxidative cyclization of N-aryl lmines: lndole synthesis from anilines and ketones. Shi, Z. Aerobic synthesis of pyrroles and dihydropyrroles from imines: palladium ii -catalyzed intramolecular c-h dehydrogenative cyclization. Zhang, C.

    enamine (CHEBI)

    Multiple oxidative dehydrogenative functionalization of arylacetaldehydes using molecular oxygen as oxidant leading to 2-oxo-acetamidines. Sibi, M. Organocatalysis in radical chemistry. Enantioselective Alpha-oxyamination of aldehydes. Van Humbeck, J.

    Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-somo activation pathway. Simonovich, S. A general approach to the enantioselective alpha-oxidation of aldehydes via synergistic catalysis. Pouliot, M.

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    Synthesis of enamines

    Li, Y. Akagawa, K. Efficient asymmetric alpha-oxyamination of aldehydes by resin-supported peptide catalyst in aqueous media. Flexible and chemoselective oxidation of amides to alpha-keto amides and alpha-hydroxy amides. Li, X.

    Search articles by author

    Selective alpha-oxyamination and hydroxylation of aliphatic amides. Crisalli, P. Importance of ortho proton donors in catalysis of hydrazone formation. Lim, H.

    Catalytic intramolecular ketone alkylation with olefins by dual activation. Lankri, D. Multifaceted alpha-enaminone: adaptable building block for synthesis of heterocyclic scaffolds through conceptually distinct 1,2-, 1,3-, 1,4-, and C-O bond forming annulations. Shi, H. Tetrahedron 70 , — Rueping, M. Fast, efficient, mild, and metal-free synthesis of pyrroles by domino reactions in water. Parsons, A. Radical cyclisation of N- cyclohexenyl acrylamides: synthesis of bicyclic N-heterocycles.

    Tetrahedron 54 , — Liang, Y. Conversion of simple cyclohexanones into catechols. Chen, Y. Palladium-catalyzed alpha,beta-dehydrogenation of esters and nitriles. Amide alpha,beta-dehydrogenation using allyl-palladium catalysis and a hindered monodentate anilide. Chen, M. Direct catalytic desaturation of lactams enabled by soft enolization. Jie, X. Cu-catalyzed sequential dehydrogenation-conjugate addition for beta-functionalization of saturated ketones: scope and mechanism.

    Shang, Y. Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates. Izawa, Y. Palladium-catalyzed aerobic dehydrogenation of substituted cyclohexanones to phenols. Diao, T. Pun, D. Hajra, A. Palladium-catalyzed aerobic dehydrogenative aromatization of cyclohexanone imines to arylamines. Girard, S. Pd-catalyzed synthesis of aryl amines via oxidative aromatization of cyclic ketones and amines with molecular oxygen. Chen, Z. Formal direct cross-coupling of phenols with amines. Taniguchi, K. Facile access to N-substituted anilines via dehydrogenative aromatization catalysis over supported gold-palladium bimetallic nanoparticles.

    Hartwig, J. Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides.